Search results for "Gas-discharge lamp"
showing 10 items of 17 documents
High-frequency electrodeless lamps in argon–mercury mixtures
2005
In this paper, numerical and experimental investigations of high-frequency (HF) electrodeless lamps in argon–mercury mixtures are performed. The intensities of the mercury spectral lines having wavelengths λ = 404.66, 435.83, 546.07 nm (7 3S1–6 3P0,1,2) and the resonance line λ = 253.7 nm (6 3 P1–6 1S0) are measured at a wide range of mercury pressures, varying the HF generator current and argon filling pressure. A stationary self-consistent model of HF electrodeless discharge lamp is developed including kinetics of the excited mercury and argon atomic states. Based on the developed model, the radiation characteristics of the discharge plasma are calculated. Numerical simulation of the line…
Determination of the number densities of argon metastables in argon-hydrogen plasma by absorption and self-absorption methods
2006
The number densities of Ar 3s23p54s levels have been measured by means of two methods: a self-absorption method with a mirror behind the discharge vessel and an absorption method with a high-frequency electrodeless discharge lamp. Concentrations ranging from 6 × 107–4 × 109 cm−3 were obtained for the Ar 3s23p54s levels, depending on the argon content (10–100% Ar) in Ar/H2 microwave plasma. The populations of various sublevels of measured resonant and metastable states coincide within the experimental errors. It was observed that values from measurements of both methods are in good agreement.
High-frequency electrodeless discharge lamps for atomic absorption analysis
2003
Abstract In this paper we present the results of an investigation of high-frequency electrodeless discharge lamps (HFEDLs), containing Cd, Zn, Hg, As, Te, Se, Pb, Sn, Tl and Bi, developed in our laboratories as light sources for atomic absorption spectrometry (AAS). Important physical processes in the lamps are discussed. Essential characteristics of HFEDLs for AAS, such as intensity, stability and operating life are considered. The intensities and detection limits are compared with the corresponding characteristics of hollow cathode lamps. The temporal behavior of an As HFEDL is compared with that of a commercially available electrodeless discharge lamp. Detection limits in graphite furnac…
A study of capillary discharge lamps in Ar–Hg and Xe–Hg mixtures
2011
Low-pressure capillary discharge lamps in Ar–Hg and Xe–Hg mixtures are studied. The discharge size is 0.5 mm (500 µm) in radius. According to the literature, such types of plasma sources are classified as microplasmas. The studies include spectrally resolved optical measurements, tomographic reconstructions and numerical simulations using the collisional–radiative model for an Ar–Hg plasma. We discuss the problems of theoretical modelling and experimental diagnostics of microplasma sources. It is shown that the conventional collisional–radiative model, based on the assumption that transportation of atoms in the highly excited states can be neglected, has limitations in modelling a capillary…
Spatial Diagnostics of Hg/Ar and Hg/Xe Discharge Lamps by Means of Tomography
2011
In this work, the diagnostics using tomography in Hg/Xe and Hg/Ar capillary lamps is presented. First, the imaging of the lamps was performed using selected emission lines of mercury, argon and xenon in different operation conditions. Thus the tomographic reconstruction was made, to determine the spatial distribution of the emitting Hg and rare gas atoms. Significant differences of the distribution of the emitting atoms have been found in vertical and horizontal operation positions. The emitting mercury atoms in the state 73S1 were differently distributed within the lamp in the vertical and horizontal lamp positions. The radial profile has demonstrated a substantial depletion of the popula…
Estimation of the emission temperature of an electrodeless discharge lamp and determination of the oscillator strength for the I(2P3/2) 183.038 nm re…
2001
Abstract The 183.038 nm resonance absorption transition of I( 2 P 3/2 ) has been studied using a flash photolysis set-up for gas-phase chemistry and a radio frequency powered electrodeless discharge lamp filled with iodine. The dependence of self-absorption and self-reversal on iodine partial pressure in the discharge volume was measured. The optimum iodine partial pressure, with self-absorption minimized and acceptable intensity, is determined to be approximately 2.5×10 −3 mbar. A method is described to estimate the temperature of the emitting atoms using direct measurements of relative absorption at different absorber concentrations. This yields an emission temperature of 923±50 K. Using …
Line Identification of Atomic and Ionic Spectra of Holmium in the Near-UV. Part I. Spectrum of Ho i
2017
The Fourier Transform spectra of a Holmium hollow cathode discharge lamp have been investigated in the UV spectral range from 25,000 up to 31,530 cm−1 (317 to 400 nm). Two Ho spectra have been measured with neon and argon as buffer gases. Based on the intensity ratios from these two spectra, a distinction was made between atomic and ionic lines (ionic lines are discussed in an accompanying paper). Using the known Ho i energy levels, 71 lines could be classified as transitions of atomic Ho, 34 of which have not been published previously. Another 32 lines, which could not be classified, are listed in the literature and assigned as atomic Ho. An additional 370 spectral lines have been assigned…
Hyperfine structure measurements of neutral niobium with Fourier transform spectroscopy
2010
Aims. We report on experimental studies of hyperfine structure splitting of neutral niobium.Methods. We used high-resolution Fourier transform spectroscopy to record a spectrum of niobium produced with a hollow cathode discharge lamp in the range of wavenumbers from 10 000 cm-1 to 30 000 cm-1 .Results. The magnetic dipole hyperfine structure constants A were determined for the 109 levels of odd parity by analyzing the profiles of 224 spectral lines. The A values of 57 of these level are reported for the first time.
Deconvolution of the spectral line profiles for the plasma temperature estimation
2010
Abstract The Hg 253.7 nm spectral line profiles, emitted from the mercury–argon high-frequency electrodeless discharge lamps (HFEDL) have been measured by means of a high-resolution scanning Fabry–Perrot interferometer at the mercury cold spot temperature value at 20 °C, different discharge current and buffer gas values. The deconvolution procedure by means of the Tikhonov's regularization method was performed to obtain the real spectral line shape. The influence of the instrumental function and absorption, real width of the Hg 253.7 nm resonance line and temperature of the radiating atoms are obtained. The results were compared with the results of the nonlinear multiparameter mathematical …
Investigation of Hg resonance 184.9nm line profile in a low-pressure mercury–argon discharge
2007
Abstract The line profiles of 184.9 nm Hg resonance line emitted from a Hg low-pressure high-frequency electrodeless discharge lamp, containing Hg 198 isotope, have been measured by means of a Zeeman scanning spectrometer at the mercury cold spot temperature values in the range of 0–23 °C. Two different methods were used to determine the real spectral line profile and to separate the instrument function: (i) solving the ill-posed inverse problem by means of the Tikhonov's regularization method; and (ii) the mathematical modelling by means of a non-linear multi-parameter chi-square fit. The real Hg 184.9 nm spectral line profiles, determined by both methods, are compared. Influence of instru…